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Screening of mgo-and ceo2 based catalysts for carbon dioxide oxidative coupling of methane to c2 hydrocarbons

Saidina Amin, Nor Aishah (2004) Screening of mgo-and ceo2 based catalysts for carbon dioxide oxidative coupling of methane to c2 hydrocarbons. Journal of Natural Gas Chemistry, 13 (1). pp. 23-35. ISSN 1003-9953

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Abstract

The catalyst screening tests for carbon dioxide oxidative coupling of methane (CO2-OCM) have been investigated over ternary and binary metal oxide catalysts. The catalysts are prepared by doping MgO- and CeO2-based solids with oxides from alkali (Li2O), alkaline earth (CaO), and transition metal groups (WO3 or MnO). The presence of the peroxide (O2?? 2 ) active sites on the Li2O2, revealed by Raman spectroscopy, may be the key factor in the enhanced performance of some of the Li2O/MgO catalysts. The high reducibility of the CeO2 catalyst, an important factor in the CO2-OCM catalyst activity, may be enhanced by the presence of manganese oxide species. The manganese oxide species increases oxygen mobility and oxygen vacancies in the CeO2 catalyst. Raman and Fourier Transform Infra Red (FT- IR) spectroscopies revealed the presence of lattice vibrations of metal-oxygen bondings and active sites in which the peaks corresponding to the bulk crystalline structures of Li2O, CaO, WO3 and MnO are detected. The performance of 5%MnO/15%CaO/CeO2 catalyst is the most potential among the CeO2-based catalysts, although lower than the 2%Li2O/MgO catalyst. The 2%Li2O/MgO catalyst showed the most promising C2+ hydrocarbons selectivity and yield at 98.0% and 5.7%, respectively. Key words: catalyst screening, carbon dioxide, oxidative coupling, methane, ternary metal oxide, binary metal oxide, MgO, CeO2, C2+ hydrocarbons

Item Type:Article
Uncontrolled Keywords:atalyst screening, carbon dioxide, oxidative coupling, methane, ternary metal oxide, binary metal oxide, MgO, CeO2, C2+ hydrocarbons
Subjects:T Technology > TA Engineering (General). Civil engineering (General)
T Technology > TP Chemical technology
Divisions:Mechanical Engineering
ID Code:28186
Deposited By: Nurul Asilah Mahmood
Deposited On:18 Sep 2012 06:16
Last Modified:18 Sep 2012 06:16

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