Engineering attributes of ternary geopolymer mortars containing high volumes of palm oil fuel ash: Impact of elevated temperature exposure

Abstract

Geopolymer mortars made from various waste products can appreciably reduce carbon dioxide emissions and landfill-related issues, making them viable substitutes for ordinary Portland cement, a workhorse in the concrete industry. Thus, a series of ternary geopolymer mortars were made and characterized to determine the effects of exposure to elevated temperatures (from room temperature up to 900 °C) on their engineered (residual compressive strength, weight loss, and slant shear bond strength) and microstructural properties. These mortars, which contain fly ash, ground blast furnace slag, and a high volume of palm oil fuel ash, were designed to activate via the incorporation of an alkali activator solution at a low concentration (molarity of 4). The elevated temperature-mediated deterioration of the ternary geopolymer mortar was quantified using Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis. The results revealed an improvement in the ternary geopolymer mortars’ resistance against elevated temperatures when the palm oil fuel ash level in the mortar matrix was raised from 50 to 70% and when slag was replaced by fly ash. It was asserted that the proposed ternary geopolymer mortars may contribute to the advancement of green concretes demanded by the construction sectors.