Biomarker characteristics of the heterocyclic and polycyclic aromatic hydrocarbons in the crude oils from West Siberian Basin, Russia: an implication for correlation with organic matter input, depositional environment and maturity.

Abstract

The distribution of aromatic hydrocarbon in sediments and oils is known to be affected by thermal maturity, source input and depositional conditions. Hence, the aromatic hydrocarbon fraction of four oil samples from different wells of the West Siberian Basin (central Russia) was investigated to determine the source of organic matter (OM), depositional environment and maturity of their source rocks. Biomarker ratios and parameters of aromatic compounds indicate that the studied oils were generated from clay-rich source rocks containing a mixed organic matter of marine and terrestrial origin, which were deposited in freshwater/deltaic to marine environmental settings under suboxic to relatively oxic conditions. Furthermore, the maturity-sensitive aromatic hydrocarbon parameters indicate that the source rocks are thermally mature, and in the peak to late maturity stage of the oil generation window. Oil–oil correlation results of various established aromatic biomarker proxies for organic matter origin, depositional environment and lithology suggests that the analyzed west Siberian Basin’s oils were generated from a variety of geological sources and can be grouped into two distinct oil families. The first oil family (group I) was generated from clay-rich source rock containing mixed organic matter with relatively high amounts of terrestrial plant input and deposited in a non-marine (freshwater/deltaic) environment under relatively oxic conditions, while the second oil family (group II) was derived from mixed organic matter with high marine OM input that was deposited in marine environment under suboxic conditions. The findings of the heterocyclic and polycyclic aromatics highlighted in this study can help for better understanding of the genetic ties between oils and their sources and have an impact on traditional hydrocarbon development in the Basin.