Surface functionalization of bauxite hollow fibre membrane using copper oxide (CuO) and its reusability for photodegradation of bisphenol A from aqueous solution

Abstract

This work developed and applied a CuO-impregnated bauxite hollow fibre membrane (BHFM) using hydrothermal method for bisphenol A (BPA) photodegradation. BHFM was synthesized through a phase inversion method at optimum sintering at 1300 °C. Subsequently, the physico-chemical properties of CuO-coated BHFM were characterized, while its performance for the BPA degradation was investigated at varying time of hydrothermal exposure and compared to ceramic hollow fibre membrane from alumina (AHFM) as control and commercial membranes. Oxidation by-products, resulting from BPA photodegradation, were identified and after treatment, the saturated membrane was regenerated to sustain its cost-effectiveness. As compared to the pristine BHFM membrane, we found that functionalizating BHFM surface with CuO significantly improved its mechanical strength by 130 % from 18.5 to 42.5 MPa. The removal of BPA was enhanced with the increasing hydrothermal time to 5 h due to the even distribution of CuO-impregnated BHMF on its membrane surface. 97 % of BPA removal with 10 mg/L concentration was substantially attained by the same CuO-impregnated BHFM under visible light (VIS) irradiation. Treated effluents, resulting from the BPA photocatalysis, could meet the required effluent limit of 20 mg/L set by national legislation. The possible oxidation by-products cover 4-(2-hydroxy-2-propanol)phenol, 4-isopropylphenol and dihydroxybenzene. With 25 % of efficiency, the saturated CuO-impregnated BHMF was subsequently regenerated for consecutive five cycles. This implies that functionalizing BHMF surface with CuO enabled it to possess outstanding stability and removal performance for treatment of BPA-laden wastewater.