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Amine functionalized radiation induced grafted polyolefin nanofibers for CO2 adsorption

Abbasi, Ali and Mahmoud Nasef, Mohamed and Kheawhom, Soorathep and Faridi-Majidi, Reza and Takeshi, Matsuura and Abouzari-Lotf, Ebrahim and Choong, Thomas (2019) Amine functionalized radiation induced grafted polyolefin nanofibers for CO2 adsorption. Radiation Physics and Chemistry, 156 . pp. 58-66. ISSN 0969-806X

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Official URL: http://dx.doi.org/10.1016/j.radphyschem.2018.10.01...

Abstract

A new type of nanofibrous amine-containing adsorbent was prepared for CO2 adsorption by electrospinning of syndiotactic polypropylene (s-PP) followed by radiation induced grafting of glycidyl methacrylate and subsequent amination with ethanolamine. The obtained adsorbents were tested for CO2 adsorption with a mixture of CO2/N2 having 5–15% CO2 using a fixed bed adsorption column at atmospheric pressure. A maximum adsorption capacity of 2.87 mmol/g was achieved for the sample with degree of grafting of 300% and degree of amination of 94% at feed concentration of 15% at 30 °C. This was accompanied by good mechanical characteristics and a very high amine efficiency that reached 75% at room temperature, suggesting that the obtained fibrous adsorbent has high potential for CO2 adsorption.

Item Type:Article
Uncontrolled Keywords:nanofibers, radiation induced grafting, solid supported adsorbent
Subjects:T Technology > TP Chemical technology
Divisions:Chemical and Energy Engineering
ID Code:89222
Deposited By: Yanti Mohd Shah
Deposited On:22 Feb 2021 14:01
Last Modified:22 Feb 2021 14:01

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