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Benzyl alcohol oxidation using gold catalysts derived from Au8 clusters on TiO2

Adnan, Rohul H. and Golovko, Vladimir B. (2019) Benzyl alcohol oxidation using gold catalysts derived from Au8 clusters on TiO2. Catalysis Letters, 149 (2). pp. 449-455. ISSN 1011-372X

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Official URL: http://dx.doi.org/10.1007/s10562-018-2625-8


Atomically-precise gold clusters have gained attraction in catalysis due to high fraction of low-coordinated gold atoms, unique structural geometry and ligand effect. Phosphine-ligated gold clusters offer an advantage in the light of the labile gold-phosphorous bond for easy ligand removal. Here, heterogeneous gold catalysts were prepared by depositing atomically-precise phosphine-ligated gold clusters, Au8(PPh3)8(NO3)2 onto anatase-phase TiO2 nanoparticles. The catalysts were then calcined under two different conditions: O2(Au8/TiO2:O2) and O2 followed by H2(Au8/TiO2:O2–H2) at 200°C, to dislodge phosphine ligands from the Au core. It was found that Au8/TiO2:O2–H2 catalyst showed a decent catalytic activity in benzyl alcohol oxidation while Au8/TiO2 and Au8/TiO2:O2 were completely inactive. Such results imply that small-size gold clusters (2–3nm) alone do not always contribute to high catalytic activity of gold catalysts. It is suggested that the presence of NO3− species defines the catalytic activity of supported gold clusters in benzyl alcohol oxidation in the case of these catalysts and reinforces our initial claim in the previous work.

Item Type:Article
Uncontrolled Keywords:alcohols, green chemistry, heterogeneous catalysis, oxidation
Subjects:Q Science > QD Chemistry
ID Code:87644
Deposited By: Yanti Mohd Shah
Deposited On:30 Nov 2020 17:06
Last Modified:30 Nov 2020 17:06

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