Universiti Teknologi Malaysia Institutional Repository

Synthesis and spectroscopic characterization of molybdenum(O) and molybdenum(II) carbonyl benzophenoneazine complexes

Affan, M. A. and Hitam, R. and Shamsuddin, M. (2002) Synthesis and spectroscopic characterization of molybdenum(O) and molybdenum(II) carbonyl benzophenoneazine complexes. Indian Journal of Chemistry - Section A Inorganics, Physical, Theoretical and Analytical Chemistry, 41 (12). 2540 -2543.

Full text not available from this repository.

Official URL: http://nopr.niscair.res.in/bitstream/123456789/184...

Abstract

A chelating 2-methylpyridylbenzophenoneazine ligand has been prepared by the condensation of 2-acetylpyridine with benzophenone hydrazone. Reaction of the ligand with Mo(CO)6 gives 12-methylpyridylbenzophenoneazine)tetracarbonylmolybdenum(0) complex where the ligand is bidentate N, N. Oxidative-addition of the tetracarbonyl complex with 1 mol equivalent of bromine, yields the neutral seven-coordinated dibromotricarbonylmolybdenum(II) azine complex. Treatment of the tetracarbonyl complex with 1 mol equivalent of PPh3 gives the expected tri-carbnonylmolybdenum(O)-azine triphenylphosphine substituted complex

Item Type:Article
Subjects:Q Science > QD Chemistry
Divisions:Science
ID Code:7804
Deposited By: Maznira Sylvia Azra Mansor
Deposited On:22 Jan 2009 07:30
Last Modified:23 Oct 2017 05:01

Repository Staff Only: item control page