Affan, M. A. and Hitam, R. and Shamsuddin, M. (2002) Synthesis and spectroscopic characterization of molybdenum(O) and molybdenum(II) carbonyl benzophenoneazine complexes. Indian Journal of Chemistry - Section A Inorganics, Physical, Theoretical and Analytical Chemistry, 41 (12). 2540 -2543.
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Official URL: http://nopr.niscair.res.in/bitstream/123456789/184...
Abstract
A chelating 2-methylpyridylbenzophenoneazine ligand has been prepared by the condensation of 2-acetylpyridine with benzophenone hydrazone. Reaction of the ligand with Mo(CO)6 gives 12-methylpyridylbenzophenoneazine)tetracarbonylmolybdenum(0) complex where the ligand is bidentate N, N. Oxidative-addition of the tetracarbonyl complex with 1 mol equivalent of bromine, yields the neutral seven-coordinated dibromotricarbonylmolybdenum(II) azine complex. Treatment of the tetracarbonyl complex with 1 mol equivalent of PPh3 gives the expected tri-carbnonylmolybdenum(O)-azine triphenylphosphine substituted complex
Item Type: | Article |
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Subjects: | Q Science > QD Chemistry |
Divisions: | Science |
ID Code: | 7804 |
Deposited By: | Maznira Sylvia Azra Mansor |
Deposited On: | 22 Jan 2009 07:30 |
Last Modified: | 23 Oct 2017 05:01 |
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