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Dichloromethyl[1-(2-pyridyl)ethanone benzoylhydrazonato]tin(IV)

Affan, M.A and Shamsuddin, M.B and Yusof, M. S M (2004) Dichloromethyl[1-(2-pyridyl)ethanone benzoylhydrazonato]tin(IV). Acta Crystallographica Section E:Structure and Reports Online, 60 (1). pp. 126-128. ISSN 1600-5368

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Official URL: http://dx.doi.org/10.1107/S1600536803028976


The chelate Sn - O - C - N - N - C - C - N fragment, together with the substituent methyl C atom, in the title complex, [SnCl2(CH 3)(C14H12N3O)], is planar, allowing the tridentate O,N,N-donor atoms and the methyl ligand C atom to occupy the equatorial positions in an octahedral environment. The geometry of the Sn atom is distorted octahedral, with a Cl - Sn - Cl axial bond angle of 172.02 (3)°.

Item Type:Article
Uncontrolled Keywords:crystal-structure, complexes
Subjects:Q Science > QD Chemistry
ID Code:7803
Deposited By: Maznira Sylvia Azra Mansor
Deposited On:22 Jan 2009 07:20
Last Modified:22 Mar 2011 04:51

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