Chacon, Cecilia and Bruno Colmenarez, Julia and Jamalis, Joazaizulfazli and Delgado, Gerzon E. (2017) Synthesis, thermal studies and crystal structure of 4-aminopyridinium semi-oxalate hemihydrate. Scientific Study and Research: Chemistry and Chemical Engineering, Biotechnology, Food Industry, 18 (2). pp. 111-119. ISSN 1582-540X
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Abstract
The title compound has been synthesized by grinding in an agate mortar. Its structure was characterized by TGA-DSC studies and single-crystal X-ray diffraction. This compound crystallize in the monoclinic system with space group C2/c, Z = 4, and unit cell parameters a = 16.109(2) Å, b = 5.748(7) Å, c = 20.580(3) Å, β = 107.36(1)°. The salt, C2HO4 -.C5H7N+.0.5 H2O, is an ionic ensemble assisted by hydrogen bonds established between 4-aminopyridinium cations, oxalate anions and water molecules. The three components thus construct a supramolecular assembly with a three-dimensional hydrogen bonded framework.
| Item Type: | Article |
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| Uncontrolled Keywords: | hydrogen bonding patterns, multicomponent crystal, X-ray diffraction |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Science |
| ID Code: | 77537 |
| Deposited By: | Widya Wahid |
| Deposited On: | 27 Sep 2018 04:14 |
| Last Modified: | 01 Dec 2020 07:56 |
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