Universiti Teknologi Malaysia Institutional Repository

Aliquat 336 stabilized multi-faceted gold nanoparticles with minimal ligand density

Naz, G. and Othaman, Z. and Shamsuddin, M. and Ghoshal, S. K. (2016) Aliquat 336 stabilized multi-faceted gold nanoparticles with minimal ligand density. Applied Surface Science, 363 . pp. 74-82. ISSN 0169-4332

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Abstract

Using Methyltrioctylammonium chloride (Aliquat 336) as a shaping and stabilizing agent for the first time, quasi-spherical and multi-faceted gold (Au) nanoparticles (NPs) are synthesized via seed mediated protocol. These slightly elongated NPs devoid of any centre of symmetry are found to possess some twin defects on their surfaces as confirmed by TEM analysis. Their Surface plasmon resonance band is evidenced at 534 nm. The growth progression is examined through the formation of translational Au NPs during the reaction. Such Aliquat 336 stabilized NPs are demonstrated to achieve minimal ligand density. This is attributed to the formation of hexagonally patterned self-assembled monolayer of ligand molecules over the surface of Au NPs. TGA and DLS experiments are performed to quantify the ligand density on the surface of these multi-faceted Au NPs. EDX, FTIR, and XPS measurements are accomplished to determine the structure and binding of ligand molecules to Au surface. Further, these NPs are found to be luminescent with violet emission under an excitation at 320 nm. The admirable features of the results suggest that our method may constitute a basis for the facile synthesis of functionalized and luminescent multi-faceted Au NPs with minimal ligand density, potential for sundry biomedical applications.

Item Type:Article
Uncontrolled Keywords:Chelation, Gold alloys, Ligands, Luminescence, Medical applications, Molecules, Nanoparticles, Photoluminescence, Self assembled monolayers, Surface plasmon resonance, Synthesis (chemical), Aliquat-336, Biomedical applications, Gold Nanoparticles, Ligand density, Methyltrioctylammonium chloride, Nanoparticle (NPs), Self-assembled patterns, Stabilizing agents, Gold
Subjects:Q Science > QC Physics
Divisions:Science
ID Code:73864
Deposited By: Haliza Zainal
Deposited On:20 Nov 2017 10:47
Last Modified:20 Nov 2017 10:47

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