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Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications

Matmin, Juan and Yuliati, Leny and Shamsuddin, Mustaffa and Lintang, Hendrik Oktendy (2014) Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications. Advanced Materials Research, 925 . pp. 228-232. ISSN 1022-6680

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Official URL: http://dx.doi.org/10.4028/www.scientific.net/AMR.9...

Abstract

Herein we report the first example of benzene-1,3,5-tricarboxamide bearing hydrophobic aminododecane side chains (1) which spontaneously forms supramolecular network by a hydrogen bonding interaction. The compound 1 was synthesized by Schotten-Baumann reaction of 1,3,5-benzenetricarbonyl trichloride and 1-aminododecane in the presence of N,N-diisopropylethylamine. Nuclear Magnetic Resonance (NMR), Mass Spectrometry (MS), and Fourier Transform Infrared (FTIR) spectroscopies have proved the successful synthesis of 1 in 93% as white powder solid. The supramolecular organization was successfully utilized for sensing of nitrate anions by deformation of the hydrogen bonding to form inactive nitroso groups.

Item Type:Article
Uncontrolled Keywords:self-assembly, supramolecules
Subjects:Q Science
Divisions:Science
ID Code:62732
Deposited By: Fazli Masari
Deposited On:05 Jun 2017 11:05
Last Modified:05 Jun 2017 11:05

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