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Influence of TiO2/TS-1 calcination on hydroxylation of phenol

Ediati, Ratna and Ulfa, Maria and Fansuri, Hamzah and Ramli, Zainab and Nur, Hadi and Prasetyoko, Didik (2014) Influence of TiO2/TS-1 calcination on hydroxylation of phenol. Journal of Mathematical and Fundamental Sciences, 46 (1). pp. 76-90. ISSN 2337-5760

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Official URL: http://dx.doi.org/10.5614/j.math.fund.sci.2014.46....

Abstract

Titanium oxide (TiO2) was impregnated on the surface of titanosilicate-1 (TiO2/TS-1) and used as catalyst for hydroxylation of phenol with hydrogen peroxide. Calcination was conducted at various temperatures (400, 500, 600 and 700°C)in order to observe the effect on the structure and physicochemical properties towards catalytic activity for producing hydroquinone. The structure and physicochemical properties of the TiO2/TS-1 catalyst were characterized by several techniques, such as X-ray diffraction (XRD), infrared spectroscopy, nitrogen adsorption, pyridine adsorption and hydrophilic measurement. The results show that by increasing the calcination temperature,the surface acidity of the catalyst was also increased. The TiO2/TS-1 catalyst calcined at 500°Cproved to be optimal for hydroquinone production, in which the anatase-rutile phase may be present dispersed on the MFI framework

Item Type:Article
Uncontrolled Keywords:anatase, calcinations phenol hydroxylation, rutile
Subjects:Q Science
Divisions:Science
ID Code:53182
Deposited By: Siti Nor Hashidah Zakaria
Deposited On:01 Feb 2016 11:54
Last Modified:19 Jul 2018 15:25

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