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The catalytic activity enhancement and biodegradation potential of free laccase and novel sol-gel laccase in non-conventional solvents

Mohidem, Nur Atikah and Mat, Hanapi (2012) The catalytic activity enhancement and biodegradation potential of free laccase and novel sol-gel laccase in non-conventional solvents. Bioresource Technology, 114 . pp. 472-477. ISSN 0960-8524

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Official URL: http://dx.doi.org/10.1016/j.biortech.2012.02.138

Abstract

The catalytic activity of free laccase and a novel sol-gel laccase (SOLAC) in ionic liquids and organic solvents was demonstrated by using 2,6-dimethoxyphenol (2,6-DMP) as a substrate. The enhancement of the catalytic activity of the SOLAC was observed and compared to the free laccase in both media. The oxidative biodegradation of o-chlorophenol as a model of phenolic environmental pollutants in organic media shows that the degradation was observed only when using water pre-saturated organic solvents or reverse micelle system. The SOLAC gave higher biodegradation rate in either aqueous or organic solvents, in which the optimum temperature was observed at 40 °C for the reverse micelle system as a reaction medium. All results demonstrated the potential use of the SOLAC for biodegradation of phenolic environmental pollutants in non-conventional media.

Item Type:Article
Uncontrolled Keywords:ionic liquids, laccase, organic solvents
Subjects:T Technology > TP Chemical technology
Divisions:Chemical Engineering
ID Code:47597
Deposited By: Narimah Nawil
Deposited On:22 Jun 2015 05:56
Last Modified:05 Mar 2019 01:59

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