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Optical properties of lithium magnesium borate glasses doped with dy3+ and sm3+ ions

Alajerami, Yaser Saleh Mustafa and Hashim, Suhairul and Wan Hassan, Wan Muhamad Saridan and Ramli, Ahmad Termizi and Kasim, Azman (2012) Optical properties of lithium magnesium borate glasses doped with dy3+ and sm3+ ions. Physica B-Condensed Matter, 40 (13). pp. 2398-2403. ISSN 0921-4526

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Official URL: http://dx.doi.org/10.1016/j.physb.2012.03.033


Several studies showed the interesting properties of trivalent lanthanide ions when doped in various types of glasses. Optical and physical properties of lithium magnesium borate glasses doped with Dy3+ then with Sm3+ ions were determined by measuring their absorption and luminescence spectra in the visible region. The absorption spectra of Dy3+ showed eight absorption bands with hypersensitive transition at 1265 nm (H-6(15/2) -> F-6(11/2)-H-6(9/2)) and three PL emission bands at 588 nm (H-4(9/2) -> H-6(15/2)), 660 nm (F-4(9/2) -> H-6(13/2)) and 775 nm (F-4(9/2) -> H-6(11/2)). Regarding the Sm3+, nine absorption bands were observed with hypersensitive transition at 1237 nm (H-6(5/2)-F-6(7/2)); the PL spectrum showed four prominent peaks at (4)G(5/2) -> H-6(5/2) (yellow color), (4)G(5/2) -> H-6(7/2) (bright orange color), (4)G(5/2) -> H-6(9/2) (orange reddish color) and (4)G(5/2) -> H-6(11/2) (red color), respectively. Finally, a series of physical parameters such as the oscillator strengths, refractive index, ions concentration, Polaron radius and other parameters were calculated for each dopant.

Item Type:Article
Uncontrolled Keywords:samarium oxide, dysprosium oxide, luminescence, optical properties, lithium magnesium borate
Subjects:Q Science > QC Physics
ID Code:47307
Deposited By: Narimah Nawil
Deposited On:22 Jun 2015 05:56
Last Modified:28 Jan 2019 03:54

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