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Catalytic performance of hybrid nanocatalyst for levulinic acid production from glucose

Ya'aini, Nazlina and Amin, Nor Aishah Saidina (2012) Catalytic performance of hybrid nanocatalyst for levulinic acid production from glucose. AIP Conference Proceedings, 1502 (1). pp. 442-453. ISSN 0094-243X

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Official URL: http://dx.doi.org/10.1063/1.4769163

Abstract

Levulinic acid is one of the potential and versatile biomass-derived chemicals. Product analysis via HPLC revealed that the heterogeneous dehydration of glucose over hybrid nanocatalyst exhibited better performance compared to single catalyst. Hybrid nanocatalyst containing H-Y zeolite and CrCl3 could substitute homogenous acid catalyst for attaining high levulinic acid yield. Different CrC3 and H-Y zeolite weight ratios of 1:1, 1:2 and 2:1 were prepared according to the wetness impregnation method. The hybrid catalyst with a 1:1 weight ratio performed better compared to others with the highest levulinic acid yield reported (93.5%) at 140 °C, 180 min reaction time, 0.1 g catalyst loading and 0.1 g glucose feed. Characterization results revealed that properties such as surface area, mesoporosity and acidic strength of the catalyst have significant effects on glucose dehydration for levulinic acid production.

Item Type:Article
Uncontrolled Keywords:AIP
Subjects:T Technology > TL Motor vehicles. Aeronautics. Astronautics
Divisions:Chemical Engineering
ID Code:46670
Deposited By: Haliza Zainal
Deposited On:22 Jun 2015 13:56
Last Modified:18 Sep 2017 09:42

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