Shamsuddin, Mustaffa and Affan, M. A. and Salam, M. A. and Ahmad, Fasihuddin and Ismail, J. and Ali, Hapipah M. (2011) Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]. Inorganica Chimica Acta, 366 (1). pp. 227-232. ISSN 0020-1693
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Official URL: http://dx.doi.org/10.1016/j.ica.2010.11.002
Abstract
The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2-4) have been synthesized and characterized by CHN analyses, molar conductivity, UV-Vis, FT-IR and H-1 NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) angstrom, b = 9.5970(2) angstrom, c = 9.4353(2) angstrom.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | spectral analyses, crystal structur |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Science |
| ID Code: | 29421 |
| Deposited By: | Yanti Mohd Shah |
| Deposited On: | 01 Apr 2013 05:49 |
| Last Modified: | 31 Jan 2022 08:41 |
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