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Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV)

Salam, Md. A. and Affan, Md. A. and Shamsuddin, Mustaffa and Ng, S. W. (2011) Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 67 (1). p. 570. ISSN 1600-5368

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Official URL: http://dx.doi.org/10.1107/S1600536810049214


The monodeprotonated Schiff base ligand in the title compound, [Sn(CH(3))(C(14)H(19)N(4)S)Cl(2)], N,N',S-chelates to the Sn atom, which is six-coordinated in an octa-hedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent mol-ecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].

Item Type:Article
Uncontrolled Keywords:single-crystal X-ray study, data-to-parameter ratio = 21.0
Subjects:Q Science
ID Code:29062
Deposited By: Yanti Mohd Shah
Deposited On:21 Feb 2013 16:11
Last Modified:22 Oct 2020 12:04

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