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Shamsuddin, Mustaffa and Salam, Md. Abdus and Affan, Md. Abu and Seik Weng, Ng (2010) Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-N)ethylidene]thiosemicarbazidato-2N1,S}methyltin(IV). Acta Crystallographica Section E-Structure Reports, E66 (5). p. 570. ISSN 1600-5368

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Official URL: http://dx.doi.org/10.1107/S1600536810014443


The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].

Item Type:Article
Subjects:Q Science
ID Code:27081
Deposited By: Liza Porijo
Deposited On:24 Jul 2012 10:15
Last Modified:13 Feb 2017 09:41

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