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High temperature liquid chromatography of tocol-derivatives on polybutadiene-coated zirconia stationary phases

Sanagi, Marsin Marsin and See, Hong Heng and Ibrahim, Wael A. W. and Naim, Ahmedy Abu (2005) High temperature liquid chromatography of tocol-derivatives on polybutadiene-coated zirconia stationary phases. Chromatographia, 61 . pp. 567-571. ISSN 00095893

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Official URL: http://dx.doi.org/10.1365/s10337-005-0565-0

Abstract

High temperature reversed-phase high performance liquid chromatography is evaluated as a new approach for the separation of vitamin E isomers (a-, ?-, d-tocopherol, and a-, ?-, d-tocotrienol) and a-tocopherol acetate. The separations of each analyte were examined by varying the eluent composition and column temperature. Using a polybutadiene-coated zirconia column at temperatures of 80°C-140°C, complete separations were achieved within 10-20 min using organic modifier (acetonitrile) in the range of 40-50%. Irregularity of the Van't Hoff analysis was noted over the temperature studied. The plot tends to deviate from linearity at higher operating temperatures (140°C and 150°C) with linear deviation errors of 12.7% and 41.6%, respectively, for the mobile phase examined.

Item Type:Article
Uncontrolled Keywords:column liquid chromatography, high temperature separations, tocopherols and tocotrienols, zirconia stationary phases
Subjects:Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions:Chemical Engineering
ID Code:12440
Deposited By: S.N.Shahira Dahari
Deposited On:01 Jun 2011 09:55
Last Modified:13 Jun 2011 06:05

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