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Effect of ligand type on CO2 adsorption over amine functionalized fibrous adsorbents

Mohamad, Noor Ashikin and Zubair, Nur Afifah and Lotf, Ebrahim Abouzari and Nasef, Mohamed M. and Ahmad, Arshad and Rasit Ali, Roshafima and Abdullah, T. A. T. and Teo, Ming Ting (2020) Effect of ligand type on CO2 adsorption over amine functionalized fibrous adsorbents. In: 8th Conference on Emerging Energy and Process Technology 2019, CONCEPT 2019, 27 - 28 November 2019, Kuala Lumpur, Malaysia.

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Official URL: http://dx.doi.org/10.1088/1757-899X/808/1/012009

Abstract

In this study, ligands originated from glycidyl methacrylate (GMA) and vinyl benzyl chloride (VBC) monomers were grafted onto fibrous polyethylene/polypropylene (PE/PP) substrate and the resulting grafted copolymers were functionalized with ethylenediamine (EDA). The changes in the chemical structure and crystallinity of the aminated adsorbents were evaluated using Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD), respectively. The PE/PP-g-PGMA-EDA adsorbent showed a CO2 adsorption capacity of 1.73 mmol/g from pure gas, which is 87% lower than that of PE/PP-g-PVBC-EDA (3.24 mmol/g) at 30 bars despite the higher density in the former adsorbent. The effect of temperature, selectivity and CO2 gas composition was further investigated for the PE/PP-g-PVBC-EDA adsorbent.

Item Type:Conference or Workshop Item (Paper)
Uncontrolled Keywords:fibrous, adsorbents
Subjects:T Technology > T Technology (General) > T201 Patents. Trademarks
Divisions:Malaysia-Japan International Institute of Technology
ID Code:92131
Deposited By: Widya Wahid
Deposited On:30 Aug 2021 04:58
Last Modified:30 Aug 2021 04:58

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