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CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state

Tsuji, T. and Shigeru, M. and Hoshina, T. A. and Yoneda, K. and Funazukuri, T. and Morad, N. A. (2017) CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state. Fluid Phase Equilibria, 441 . pp. 9-16. ISSN 0378-3812

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Abstract

Carbon dioxide (CO2) solubility was measured in aqueous solutions containing 0.6 wt% D(+)-galacturonic acid (GalH) or sodium D(+)-galacturonate (GalNa) by use of a recirculating apparatus at 313.4 K and at pressures up to 9.29 MPa. The solubilities of CO2 in the two solutions containing GalH or GalNa were similar to those in pure water. The experimental data were correlated with the Peng-Robinson-Stryjek-Vera (PRSV) equation of state. A new method was developed to estimate pH by use of the molar volume from the PRSV equation and compared with measured pH values. It gives some idea of the quantitative agreement between the equation of states and the measured pH values over the same range of conditions.

Item Type:Article
Uncontrolled Keywords:Carbon dioxide (CO2), galacturonic acid (GalH)
Subjects:T Technology > T Technology (General)
Divisions:Malaysia-Japan International Institute of Technology
ID Code:76179
Deposited By: Widya Wahid
Deposited On:25 Jun 2018 09:06
Last Modified:25 Jun 2018 09:06

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