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Phase transition kinetics and surface binding states of methylammonium lead iodide perovskite

Rajendra Kumar, G. and Dennyson Savariraj, A. and Karthick, S. N. and Selvam, S. and Balamuralitharan, B. and Kim, H. J. and Viswanathan, K. K. and Vijaykumar, M. and Prabakar, K. (2016) Phase transition kinetics and surface binding states of methylammonium lead iodide perovskite. Physical Chemistry Chemical Physics, 18 (10). pp. 7284-7292. ISSN 1463-9076

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Abstract

We have presented a detailed analysis of the phase transition kinetics and binding energy states of solution processed methylammonium lead iodide (MAPbI3) thin films prepared at ambient conditions and annealed at different elevated temperatures. It is the processing temperature and environmental conditions that predominantly control the crystal structure and surface morphology of MAPbI3 thin films. The structural transformation from tetragonal to cubic occurs at 60 °C with a 30 minute annealing time while the 10 minute annealed films posses a tetragonal crystal structure. The transformed phase is greatly intact even at the higher annealing temperature of 150 °C and after a time of 2 hours. The charge transfer interaction between the Pb 4f and I 3d oxidation states is quantified using XPS.

Item Type:Article
Uncontrolled Keywords:methylammonium lead iodide (MAPbI3) thin films
Subjects:Q Science > QA Mathematics
Divisions:Science
ID Code:73728
Deposited By: Haliza Zainal
Deposited On:18 Nov 2017 03:21
Last Modified:18 Nov 2017 03:21

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