Universiti Teknologi Malaysia Institutional Repository

Generation of Brönsted acidity in AlMCM-41 by sulphation for enhanced liquid phase tert-butylation of phenol

Nur, Hadi and Hamdan, Halimaton and Ng, Eng Poh and Wong, Ka Lun and Muhid, Mohd Nazlan Mohd (2007) Generation of Brönsted acidity in AlMCM-41 by sulphation for enhanced liquid phase tert-butylation of phenol. Applied Catalysis A:General, 323 . pp. 58-65. ISSN 0926-860X

Full text not available from this repository.

Official URL: http://dx.doi.org/10.1016/j.apcata.2007.02.001

Abstract

AlMCM-41 mesoporous molecular sieve modified by impregnation with sulphuric acid in toluene possesses only Brönsted acid sites. The catalyst exhibits a high catalytic activity for tert-butylation of phenol with high selectivity to 2,4-di-tert-butylphenol in liquid phase. 27Al MAS NMR study indicates that the modification of AlMCM-41 with sulphuric acid in toluene leaves only octahedrally coordinated Al species. The tetrahedrally coordinated Al species which exist before modification with sulphuric acid in toluene being dealuminated to form extraframework octahedrally coordinated Al species. The mesoporous structure of AlMCM-41 is retained after modification, but pore size decreases by ca. 3 Å by the modification. The active sites are postulated on the basis of XRD, FTIR, 27Al MAS NMR, TGA, BET analysis and FTIR-pyridine adsorption studies that -OSO3H bonded to octahedrally coordinated Al species.

Item Type:Article
Uncontrolled Keywords:AlMCM-41, brönsted acid, phenol, sulphation, tert-Butylation
Subjects:Q Science > QD Chemistry
Divisions:Science
ID Code:7316
Deposited By: Maznira Sylvia Azra Mansor
Deposited On:01 Jan 2009 07:13
Last Modified:01 Jan 2009 07:13

Repository Staff Only: item control page