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Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A

Hamdan, Halimaton and Navijanti, Vivin and Nur, Hadi and Muhid, Mohd Nazlan Mohd (2005) Fe(III)-salen encapsulated Al-MCM-41 as a catalyst in the polymerisation of bisphenol-A. Solid State Sciences, 7 (2). pp. 239-244. ISSN 1293-2558

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Official URL: http://dx.doi.org/10.1016/j.solidstatesciences.200...

Abstract

Fe(III)-salen complexes encapsulated in the channels of Al-MCM-41 molecular sieves were successfully synthesised in situ by the flexible ligand method. The resulting compound was characterised by XRD, IR spectroscopy, nitrogen adsorption isotherm and 1H NMR techniques. The loading of complexes in Al-MCM-41 depends on the quantity of framework aluminium, suggesting that there is an electrostatic interaction between the positive charges of the encapsulated Fe(III)-salen complexes and the negative charges of the Al-MCM-41 framework. Polymerisation of bisphenol-A catalysed by Fe(III)-salen-Al-MCM-41 gave 67% conversion; significantly higher than the conventional homogeneous Fe(III)-salen catalyst.

Item Type:Article
Uncontrolled Keywords:Encapsulated Fe(III)-salen-Al-MCM-41, zeozyme catalyst, polymerisation, bisphenol-A
Subjects:T Technology > TP Chemical technology
Divisions:Chemical and Natural Resources Engineering (Formerly known)
ID Code:7298
Deposited By: Maznira Sylvia Azra Mansor
Deposited On:01 Jan 2009 06:44
Last Modified:01 Jan 2009 06:44

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