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Impact of Eu3+ ions on physical and optical properties of Li2O-Na2O-B2O3 glass

Razak, N. A. and Hashim, S. and Mhareb, M. H. A. and Alajerami, Y. S. M. and Azizan, S. A. and Tamchek, N. (2016) Impact of Eu3+ ions on physical and optical properties of Li2O-Na2O-B2O3 glass. Chinese Journal of Chemical Physics, 29 (3). pp. 395-400. ISSN 1674-0068

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Abstract

The lithium sodium borate glasses doped with Eu3+ ion are prepared using melt quenching technique, their structural and optical properties have been evaluated. The density of prepared glasses exhibits an inverse behavior to the molar volume ranging from 2.26 g/cm3 to 2.43 g/cm3 and 26.95 cm3/mol to 26.20 cm3/mol, respectively. The absence of sharp peaks in XRD patterns confirms the amorphous nature of the prepared glasses. The absorption spectra yield four transitions centered at 391 nm (7F0→5L6), 463 nm (7F0→5D2), 531 nm (7F0→5D1), and 582 nm (7F0→5D0). The most intense red luminescence is observed at 612 nm corresponding to 5D0→7F2 transition under 390 nm laser excitations.

Item Type:Article
Uncontrolled Keywords:absorption, borate glass, europium oxide
Subjects:Q Science > QC Physics
Divisions:Science
ID Code:72397
Deposited By: Narimah Nawil
Deposited On:20 Nov 2017 08:23
Last Modified:20 Nov 2017 08:23

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