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Enhancement of fuel cell performance with less-water dependent composite membranes having polyoxometalate anchored nanofibrous interlayer

Abouzari lotf, E. and Jacob, M. V. and Ghassemi, H. and Ahmad, A. and Nasef, M. M. and Zakeri, M. and Mehdipour Ataei, S. (2016) Enhancement of fuel cell performance with less-water dependent composite membranes having polyoxometalate anchored nanofibrous interlayer. Journal of Power Sources, 326 . pp. 482-489. ISSN 0378-7753

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Abstract

Polyoxometalate immobilized nanofiber was used to fabricate low gas permeable layer for composite membranes designed for proton exchange membrane fuel cell (PEMFC) operating at low relative humidity (RH). The composite membranes revealed enhanced proton conductivity in dry conditions compared with state-of-the-art pristine membrane (Nafion 112, N112). This was coupled with a low fuel crossover inheriting the composite membranes about 100 mV higher OCV than N112 when tested in PEMFC at 60 °C and 40% RH. A maximum power density of up to 930 mW cm−2 was also achieved which is substantially higher than the N112 under similar conditions (577 mW cm−2). Such remarkable performance enhancement along with undetectable leaching of immobilized polyoxometalate, high dimensional stability and low water uptake of the composite membranes suggest a strong potential for PEMFC under low RH operation.

Item Type:Article
Uncontrolled Keywords:Composite membranes, Electrolytes, Fuel cells, Gas permeable membranes, Membranes, Nanofibers, Oxides, Polyelectrolytes, High dimensional stability, High energy densities, Low relative humidities, Maximum power density, Membrane electrode assemblies, Nanofibrous membranes, Performance enhancements, Polyoxometalates, Proton exchange membrane fuel cells (PEMFC)
Subjects:T Technology > TP Chemical technology
Divisions:Chemical Engineering
ID Code:71555
Deposited By: Widya Wahid
Deposited On:20 Nov 2017 08:28
Last Modified:20 Nov 2017 08:28

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