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Experimental study of catalytic degradation of polypropylene by acid-activated clay and performance of Ni as a promoter

Uzair, M. A. and Waqas, A. and Khoja, A. H. and Ahmed, N. (2016) Experimental study of catalytic degradation of polypropylene by acid-activated clay and performance of Ni as a promoter. Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 38 (24). pp. 3618-3624. ISSN 15567-036

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Abstract

Catalytic and thermal cracking of polypropylene was performed in a batch reactor. Effect of hydrochloric acid activation on kaolin clay, effects of catalysts (acid-activated clays), promoter (5 wt% Ni), and cracking temperatures on the liquid oil yield were investigated. Results show optimized liquid yield (71.9%) obtained at 470°C with kaolin clay activated with 3 M HCl. Acid-activated catalysts were analyzed using XRD and the results reveal the reduction in peaks’ intensities. Weight loss of polypropylene was investigated by thermogravimetric analysis. FTIR and GCMS techniques were employed to analyze the liquid products.

Item Type:Article
Uncontrolled Keywords:Batch reactors, Catalysts, Catalytic cracking, Chemical activation, Clay, Cracking (chemical), Cracks, Hydrocarbons, Kaolin, Liquids, Nickel, Thermogravimetric analysis, Acid activated clay, Acid activation, Catalytic degradation, Catalytic pyrolysis, Kaolin clay, Liquid products, Liquid yield, Thermal cracking, Polypropylenes
Subjects:T Technology > TP Chemical technology
Divisions:Chemical Engineering
ID Code:71514
Deposited By: Fazli Masari
Deposited On:15 Nov 2017 03:20
Last Modified:15 Nov 2017 03:20

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