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Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II)

Kadir, Faraidoon Karim and Shamsuddin, Mustaffa and Rosli, Mohd. Mustaqim (2016) Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II). Acta Crystallographica Section E-Crystallographic Communications, 72 . pp. 760-765. ISSN 2056-9890

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Official URL: http://dx.doi.org/10.1107/S2056989016006873

Abstract

In the asymmetric unit of the title complex, [Ni(C16H14N3OS)(2)], the nickel ion is tetracoordinated in a distorted square-planar geometry by two independent molecules of the ligand which act as mononegative bidentate N,S-donors and form two five-membered chelate rings. The ligands are in trans (E) conformations with respect to the C=N bonds. The close approach of hydrogen atoms to the Ni2+ atom suggests anagostic interactions (Ni center dot center dot center dot H-C) are present. The crystal structure is built up by a network of two C-H center dot center dot center dot O interactions. One of the interactions forms inversion dimers and the other links the molecules into infinite chains parallel to [100]. In addition, a weak C-H center dot center dot center dot pi interaction is also present.

Item Type:Article
Subjects:Q Science > QD Chemistry
Divisions:Science
ID Code:69115
Deposited By: Siti Nor Hashidah Zakaria
Deposited On:01 Nov 2017 04:58
Last Modified:20 Nov 2017 08:52

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