Sandwich structure polymer electrolyte membranes containing phosphotungstic acid immobilized electospun nanofibers

Abstract

The advances in proton exchange membranes (PEM)s is critical for improving the performance of fuel cells [1]. Membranes compromising perfluorosulfonic acid polymers such as Nafion have been used extensively due to their desired conductivity and stability. However, these materials need to be saturated with water to obtain practical level of proton conductivity. There is a strong demand for the PEMs to work at lower relative humidity or under anhydrous conditions because the electrochemical reactions will be accelerated and water management of fuel cell will be simpler. Various designing strategies and advanced materials have been developed to mitigate for this issue without causing serious loss in proton conductivity or stability [2]. Among all, the introducing of inorganic proton conductors such as heteropoly acids have been considered widely. Generally, HPAs (such as phosphotungstic acid H3PW12O40, PWA) have a very strong Brønsted acidity approaching the superacid region (more acidic than Nafion) [3]. In this work, high level of PWA was self-anchored onto nylon electrospun nanofiberous sheet (Figure 1b). Sandwich structured proton conducting membranes were fabricate by assembling nanofibrous central layer with outer Nafion layers (Figure 1b). Since the PWA is attached to the polymer backbones, the risk of leaching out is minimized. Moreover, the significant synthetic versatility of the method helps to increase PWA immobilization level. As shown in the Figure 1c, proton conductivity of as high as 60 mS cm-1 at 30 °C was achieved which is comparable with Nafion 115. The durability of the proton conductivity of sandwiched membrane.