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Synthesis and electrocatalytic performance of atomically ordered nickel carbide (Ni3C) nanoparticles

Fadil, Nor Akmal and Saravanan, Govindachetty and Ramesh, Gubbala V. and Matsumoto, Futoshi and Ueda, Shigenori and Tanabe, Toyokazu and Hara, Toru and Ishihara, Shinsuke and Murakami, Hideyuki and Ariga, Katsuhiko and Abe, Hideki (2014) Synthesis and electrocatalytic performance of atomically ordered nickel carbide (Ni3C) nanoparticles. Chemical Communications, 50 (49). pp. 6451-6453. ISSN 1364-548X

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Official URL: https://dx.doi.org/10.1039/C4CC01336K

Abstract

Atomically ordered nickel carbide, Ni3C, was synthesized by reduction of nickel cyclopentadienyl (NiCp2) with sodium naphthalide to form Ni clusters coordinated by Cp (Ni-Cp clusters). Ni-Cp clusters were thermally decomposed to Ni3C nanoparticles smaller than 10 nm. The Ni3C nanoparticles showed better performance than Ni nanoparticles and Au nanoparticles in the electrooxidation of sodium borohydride.

Item Type:Article
Uncontrolled Keywords:metallic carbides, tungsten
Subjects:T Technology > TJ Mechanical engineering and machinery
Divisions:Mechanical Engineering
ID Code:62778
Deposited By: Fazli Masari
Deposited On:14 Jun 2017 00:38
Last Modified:14 Jun 2017 00:38

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