Fun, Hoong-Kun and Tze, Shyang Chia and Mahesh, Padaki and Isloor, Arun M. and Ismail, Ahmad Fauzi (2012) (2E)-3-(6-Methoxynaphthalen-2-yl)-1-[4-(methylsulfanyl)phenyl]prop-2-en-1-one. Acta Crystallographica Section E-Structure Reports Online, 68 (7). pp. 2277-2278. ISSN 1600-5368
Full text not available from this repository.
Official URL: https://doi.org/10.1107/S1600536812028930
Abstract
The asymmetric unit of the title compound, C21H18O2S, consists of two crystallographically independent molecules (A and B). The molecules exist in a trans conformation with respect to the central C=C bond. The naphthalene ring system makes dihedral angles of 51.62 (12) (molecule A) and 52.69 (12)° (molecule B) with the benzene ring. In molecule A, the prop-2-en-1-one group forms dihedral angles of 22.84 (15) and 29.02 (12)° with the adjacent naphthalene ring system and benzene ring, respectively, whereas the corresponding angles are 30.04 (12) and 23.33 (12)° in molecule B. In the crystal, molecules are linked by intermolecular C-H...O hydrogen bonds into head-to-tail chains along the a axis. The crystal packing also features C-H...[pi] interactions. The crystal studied was a pseudo-merohedral twin with twin law (100 0-10 00-1) and a refined component ratio of 0.6103 (16):0.3897 (16)..
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | crystallographica |
| Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
| Divisions: | Chemical Engineering |
| ID Code: | 46460 |
| Deposited By: | Siti Nor Hashidah Zakaria |
| Deposited On: | 22 Jun 2015 05:56 |
| Last Modified: | 30 Sep 2017 08:11 |
Repository Staff Only: item control page
