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Optimization of levulinic acid from lignocellulosic biomass using a new hybrid catalyst

Ya’aini, Nazlina and Saidina Amin, Nor Aishah and Mohammed Yussuf, Mohd. Asmadi (2012) Optimization of levulinic acid from lignocellulosic biomass using a new hybrid catalyst. Bioresource Technology, 116 . pp. 58-65. ISSN 0960-8524

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Official URL: http://dx.doi.org/10.1016/j.biortech.2012.03.097

Abstract

Conversion of glucose, empty fruit bunch (efb) and kenaf to levulinic acid over a new hybrid catalyst has been investigated in this study. The characterization and catalytic performance results revealed that the physico-chemical properties of the new hybrid catalyst comprised of chromium chloride and HY zeolite increased the levulinic acid production from glucose compared to the parent catalysts. Optimization of the glucose conversion process using two level full factorial designs (2 3) with two center points reported 55.2% of levulinic acid yield at 145.2°C, 146.7min and 12.0% of reaction temperature, reaction time and catalyst loading, respectively. Subsequently, the potential of efb and kenaf for producing levulinic acid at the optimum conditions was established after 53.2% and 66.1% of efficiencies were reported. The observation suggests that the hybrid catalyst has a potential to be used in biomass conversion to levulinic acid.

Item Type:Article
Uncontrolled Keywords:Optimization, Response surface methodology
Subjects:T Technology > TP Chemical technology
Divisions:Chemical Engineering
ID Code:32985
Deposited By: Fazli Masari
Deposited On:31 Jul 2013 05:37
Last Modified:30 Nov 2018 06:33

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