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Effects of Ni and Pd metals catalyst on Gamma Alumina support

Yaakob, Z. and Yosfiah, M. R. and Minggu, L.J. and Ibrahim, M.A. and Daud, W.R.W. (2006) Effects of Ni and Pd metals catalyst on Gamma Alumina support. In: 1st International Conference on Natural Resources Engineering & Technology 2006, 24-25th July 2006, Putrajaya, Malaysia.

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Abstract

Catalysts containing Ni or combinations of Pd, Cu and Zn on gamma alumina support have been developed for testing in autothermal methanol reforming reaction. The hydrogen produced by the catalytic reforming of methanol is targeted to be used as a feed for fuel cell. The reaction for reforming of methanol can be performed at low temperature and pressure in the presence of catalysts with high yield and low CO. The calcined catalysts has been characterized by Brunauer, Emmett and Teller (BET) for surface area, Scanning Electron Microscopy (SEM) for shape and dispersion of metals, Powder X-ray diffraction (XRD) for species present and degree of crystallinity and Temperature Programmed Reduction (TPR) for reducible species presence, their interaction and degree of reducibility. The catalyst has specific characteristic in physical and chemical properties due to the location of Ni metal on the surface of the ?-Al2O3. The effects could be observed in colour, SEM, and the total number of pores of the catalyst. The amount of metal in the supporting material ?-Al2O3 also influenced the physical properties of the catalysts. From the catalyst produced with various concentration, it is found that the content of Ni metal with specific amount, fill the channels on the surface of supporting material ?-Al2O3. Based on the catalyst activities data, suitable catalyst to produced hydrogen can be formulated.

Item Type:Conference or Workshop Item (Paper)
Uncontrolled Keywords:Nickel; Pd; Cu catalyst; Gamma alumina; Hydrogen production
Subjects:T Technology > TP Chemical technology
Divisions:Chemical and Natural Resources Engineering (Formerly known)
ID Code:294
Deposited By: Cik Rasyidah Mohd Daud
Deposited On:15 Feb 2007 10:16
Last Modified:01 Jun 2010 02:42

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