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Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)

Md. Abdus, Salam and Md. Abu, Affan and Shamsuddin, Mustaffa and Ng, Seik Weng (2010) Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV). Acta Crystallographica Section E-Structure Reports Online, 66 (5). p. 570. ISSN 1600-5368

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Official URL: http://dx.doi.org/10.1107/S1600536810014443

Abstract

The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].

Item Type:Article
Uncontrolled Keywords:Cl atom, hydrogen bond
Subjects:Q Science
Divisions:Science
ID Code:28984
Deposited By: Yanti Mohd Shah
Deposited On:07 Dec 2012 00:27
Last Modified:28 Feb 2022 13:25

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