Universiti Teknologi Malaysia Institutional Repository

The upconversion of co-doped Nd3+/Er3+ tellurite glass

Kasim, Azman (2010) The upconversion of co-doped Nd3+/Er3+ tellurite glass. In: World Academy of Science, Engineering and Technology, WASET 2010, 28-30 April 2010, Rome, Italy.

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Official URL: http://www.waset.org/journals/waset/v64/v64-76.pdf...

Abstract

Series of tellurite glass of the system 78TeO2-10PbO- 10Li2O-(2-x)Nd2O3-xEr2O3, where x = 0.5, 1.0, 1.5 and 2.0 was successfully been made. A study of upconversion luminescence of the Nd3+/Er3+ co-doped tellurite glass has been carried out. From Judd-Ofelt analysis, the experimental lifetime, t exp . of the glass serie are found higher in the visible region as they varies from 65.17ms to 114.63ms, whereas in the near infrared region (NIR) the lifetime are varies from 2.133ms to 2.270ms. Meanwhile, the emission cross section, s results are found varies from 0.004 x 1020 cm2 to 1.007 x 1020 cm2 with respect to composition. The emission spectra of the glass are found been contributed from Nd3+ and Er3+ ions by which nine significant transition peaks are observed. The upconversion mechanism of the co-doped tellurite glass has been shown in the schematic energy diagrams. In this works, it is found that the excited state-absorption (ESA) is still dominant in the upconversion excitation process as the upconversion excitation mechanism of the Nd3+ excited-state levels is accomplished through a stepwise multiphonon process. An efficient excitation energy transfer (ET) has been observed between Nd3+ as a donor and Er3+ as the acceptor. As a result, respective emission spectra had been observed.

Item Type:Conference or Workshop Item (Paper)
Uncontrolled Keywords:tellurite luminescence spectra
Subjects:T Technology > TA Engineering (General). Civil engineering (General)
Divisions:Civil Engineering
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Biosciences and Bioengineering (Formerly known)
Built Environment
Business and Advances Technology (Formerly known)
Chemical and Natural Resources Engineering (Formerly known)
Chemical Engineering
Computer Science and Information System (Formerly known)
ID Code:24368
Deposited By: Liza Porijo
Deposited On:18 Sep 2012 05:17
Last Modified:18 Sep 2012 05:17

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