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Performance Study Of Carbon-Clad Zirconia Stationary Phase In High Temperature Reversed-Phase High Performance Liquid Chromatography

Sanagi, Mohd. Marsin and See, Hong Heng and Francis, Jaclyn Ann (2005) Performance Study Of Carbon-Clad Zirconia Stationary Phase In High Temperature Reversed-Phase High Performance Liquid Chromatography. Jurnal Teknologi C (43C). pp. 15-26. ISSN 0127-9696

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Official URL: http://www.penerbit.utm.my/onlinejournal/43/C/JTDI...

Abstract

The performance of carbon-clad zirconia (CCZ) stationary phase was evaluated for the separations of test compounds (benzaldehyde, benzamide, nitrobenzene, and toluene) and alkyl aryl ketones (acetophenone, propiophenone, butyrophenone and valerophenone) at high temperature (100˚C-160˚C) in reversed-phase high performance liquid chromatography (RP-HPLC) using low compositions of organic modifier and 100% pure water as eluent. Improved separation mechanism and faster analysis time were achieved during high operating temperatures. Van’t Hoff plots were linear for the investigated CCZ column, which showed that over the temperature range, no changes occurred in the retention mechanism. The use of alkyl aryl ketone homologs as a retention index scale in high temperature RP-HPLC was investigated. Although the retention factors of the test compounds were greatly affected by increasing the column temperature, there were only slight variations in their respective retention index values.

Item Type:Article
Uncontrolled Keywords:Carbon-clad zirconia, high temperature high performance liquid chromatography
Subjects:Q Science > QD Chemistry
Divisions:Science
ID Code:1388
Deposited By: En Mohd. Nazir Md. Basri
Deposited On:05 Mar 2007 01:35
Last Modified:07 Nov 2010 05:25

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