Nur, Hadi and Misnon, Izan Izwan and Hamdan, Halimaton (2009) Alkylsilylated gold loaded magnesium oxide aerogel catalyst in the oxidation of styrene. Catalysis Letters , 130 (1-2). pp. 161-168. ISSN 1011372X
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Official URL: http://dx.doi.org/10.1007/s10562-009-9843-z
Abstract
Aerogel-prepared magnesium oxide (A-MgO) was modified by attachment of gold particles. Subsequent modification of its surface with alkylsilylation of n-octadecyltrichlorosilane and chlorotrimethylsilane exhibits a high catalytic activity for oxidation of styrene with tert-butyl hydroperoxide in liquid phase. Catalytic results show that the introduction of gold on the surface of A-MgO gives a higher catalytic activity in styrene oxidation compared to titanium dioxide. The effect of surface modification of A-MgO was studied with XRD, UV-Vis DR, FTIR and nitrogen adsorption analysis.
Item Type: | Article |
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Uncontrolled Keywords: | A-MgO, chlorotrimethylsilane, gold, octadecyltrichlorosilane, styrene oxidation, titanium dioxide |
Subjects: | Q Science > QD Chemistry |
Divisions: | Science |
ID Code: | 12958 |
Deposited By: | Zalinda Shuratman |
Deposited On: | 07 Jul 2011 08:09 |
Last Modified: | 07 Jul 2011 08:09 |
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